PPDT2FBT

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Description

PPDT2FBT, also known as PCE9.3, achieves high efficiency in organic photovoltaic devices (PCE = 9.3%) and offers a long-term thermal stability. It is also used as a hole transport layer in perovskite solar cells (PSC) to enhance the performance (PCE = 18.8%) and the stability of the device compared to the usual spiro-OMeTAD.
A high-performance red selective organic photodiode was also developed using PPDT2FBT as a photoactive donor layer (peak detectivity up to 3.04 × 10¹² Jones).

References
OPV:
[1] Nguyen, T. L.; Choi, H.; Ko, S.-J.; Uddin, M. A.; Walker, B.; Yum, S.; Jeong, J.-E.; Yun, M. H.; Shin, T. J.; Hwang, S.; Kim, J. Y. Woo, H. Y. Energy Environ. Sci. 2014, 7, 3040-3051.
[2] Lee, T. H.; Uddin, M. A.; Zhong, C.; Ko, S.-J.; Walker, B.; Kim, T.; Yoon, Y. J.; Park, S. Y.; Heeger, A. J.; Woo, H. Y.; Kim, J. Y. Adv. Energy Mater. 2016, 6, 1600637.
PSC:
[3] Koh, C. W.; Heo, J. H.; Uddin, M.; A.; Kwon, Y.-W.; Choi, D. H.; Im, H. S.; Woo, H. Y. ACS Appl. Mater. Interfaces, 2017, 9, 43846–43854.
OPD:
[4]Yoon, S.; Koh, C. W.; Woo, H. Y.; Chung, D. S. Adv. Optical Mater. 2018, 6, 1701085.

Technical specs

• CATALOG NAME

  PPDT2FBT

• NAME

  Poly[(2,5-bis(2-hexyldecyloxy)phenylene)-alt-(5,6-difluoro-4,7-di(thiophen-2-yl)benzo[c]-[1,2,5]thiadiazole)]

• Synonym

  PCE9.3, FBT

• CAS NUMBER

  1620673-07-5

• FORMULA

  P(C52H72F2N2O2S3)n

• MW

  70 – 100 kg/mol

• HOMO

  -5.45 eV

• LUMO

  -3.69 eV

• APPLICATIONS

  p-type material in Organic Photovoltaic (OPV), hole interlayer material in Perovskite Solar Cells (PSC) and photoactive donor layer for red selective organic photo diode (OPD).

Documentation

• MSDS